2020/2021 WAEC/NECO Answers: 2021 neco Chemistry practical answers

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Make sure you use your school titre value

For example, if your school uses 23.50

Our own solution centre may use 24.00

Pls don't be confused, just make adjustment from the beginning where you will need to find the *VOLUME. OF ACID USED(CA)*



EXAMPLES FOR 22.50cm³

Volume. Of acid used= 1st + 2nd + 3rd/3

=24.00+24.00+24.00 / 3


= 72/3

=24 molperdm³


VOLUME. OF ACID USE for 25.00


VA= 25.00+25.00+25.00 DIVIDED BY 3

=75/3

===================================

(1)
The volume or pipette used 25.00cm³

In a tabular form
Titrations     |rough |1st|2nd|3rd|
Final reading  |21.00|41.30|20.40|40.90
Initial reading|0.00|21.00|0.00|20.40
Vol of A used  |21.00|20.30|20.40|20.50

(1ai)
Average volume of A = 20.30+20.40+20.50/3
=61.2/3
=20.40cm³

(1aii)
H2X(aq) + 2NaOH(aq)-->Na2X(aq) + 2H2O(l)

(1bi)
Mass conc. of B = 1g/250cm³
= 1g/0.25dm³ = 4g/dm³
Using :
Molar conc. = mass conc./molar mass
= 4/(23+16+1) = 4/40 = 0.1mol/dm³

(1bii)
Using CAVA/CBVB = nA/nB
CA = CBVBnA/VAnB
CA = 0.1×25×1/20.4×2
Concentration of A = 0.06127mol/dm³

1C

(i)it might contain traces of impurities which must be removed before being weighed
(ii)it is hygroscopic which readily absorb moisture from atmosphere

==========================================
NO2

1st line:|test|:Xn +distilled water,|observat
ion|:Xn dissolves in distilled water,|inference|:Xn is a soluble salt
= = = = = = = = = == = = = =
2nd line:|test|:1st portion+NAOH in drops and in excess,|observation|:pale blue ppt,|inference|:CU2+
= = = = = = = = == = = == =
3rd line:|test|:2nd portion+NH3 in drop and in excess,|observation|:deep blue ppt,|inference|
:CU2+
= == = = = = = == == = = = =
4th line:|test|3rd portion+BACL2,|
observation|:white ppt,|inference|
:SO42-,SO32-,CO32-,CL-
= = = = = = === = == = = == =
5th line:|test|:+ dil HCL,|observation|:insoluble in HCL,|Inference|:SO42-

Still the same

(2)
FILL IN THE TABLE:

(2i)
OBSERVATION:
Solution turns blue

INFERENCE:
Copper salt suspected.

(2ii)
OBSERVATION:
Blue gelatinous precipitate

Insoluble in excess NaOH

INFERENCE:
Cu²+ suspected

Cu²+ Confirmed

(2iii)
OBSERVATION:
Blue gelatinous precipitate

Soluble in excess NH³

INFERENCE:
Cu²+ Suspected

Cu²+ Confirmed

(2iv)
OBSERVATION:
White precipitate

INFERENCE:
SO4²- Suspected

(2v)
OBSERVATION:
Precipitate insoluble in excess

INFERENCE:
SO4²- confirmed

==≠=============≠===================

(3ai)
phenolphthalein

(3aii)
I. Pink
ll. Colourless

(3aiii)
(i)To give a sharp change in colour at the end of the acid base reaction

(3aiv)
(i)the burette must be rinsed with the acid or allow it to drain after rinsing with distilled water
(ii)Air bubble must not be allowed in the burette

(3av)
Neutralization reaction

(3bi)
I. Hofmann voltameter.
II. Kipp's apparatus

(3bii)

Because silver nitrate is photosensitive (i.e.sensitive to light) Therefore,if the silver nitrate is left in sunlight or any bright light, it breaks down (hydrolyses) to give black/brown silver oxide and nitric acid.

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